Date of Award

January 2015

Degree Type

Dissertation

Degree Name

Doctor of Philosophy (PhD)

Department

Chemical Engineering

First Advisor

Fabio H Ribeiro

Second Advisor

W. N Delgass

Committee Member 1

Jeffrey P Greeley

Committee Member 2

Dmitry Y Zemlyanov

Abstract

An integrated approach for biomass upgrading to fuels requires catalyst synthesis, characterization, and kinetic evaluation. The work was divided in three areas, 1-preparation and characterization of model catalysts containing metal oxide overcoats and metal nanoparticles synthesized by atomic layer deposition (ALD), a gas-phase material deposition technique, 2-the study of structure sensitivity for formic acid decomposition on planar Pt catalysts, and 3-characterization of bimetallic Pt-M (M = Re, Mo) catalysts using surface sensitive techniques and theory.

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