Abstract

A single, self-assembled layer of highly uniform dielectric alumina nanoparticles improves the photovoltaic performance of organic semiconductor bulk heterojunction solar cells. The block copolymer based self-assembly approach is readily amenable to the large areas required for solar cell fabrication. A fraction of the performance gain results from incident light scattering which increases active layer absorption and photocurrent output, consistent with device simulations. The nanoparticle layer also roughens the device electrode surface, increasing contact area and improving device fill factor through more efficient charge collection

Comments

Copyright (2012) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters and may be found at http://dx.doi.org/10.1063/1.4744928. The following article has been submitted to/accepted by Applied Physics Letters. Copyright (2012) Jonathan E. Allen, Biswajit Ray, M. Ryyan Khan, Kevin G. Yager, Muhammad A. Alam, and Charles T. Black. This article is distributed under a Creative Commons Attribution 3.0 Unported License.

Keywords

Organic Solar Cell, Morphology, Bulk Heterojunction, Alumina Nanoparticles

DOI

10.1063/1.4744928

Citation

Applied Physics Letters: Volume 101, Issue 6

Date of this Version

2012

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