Material property prediction of thermoset polymers by molecular dynamics simulations

Abstract

Molecular dynamics simulations are conducted to predict thermal and mechanical properties of a family of thermoset polymers. We focus on the effect of cross-linkers on density, glass transition temperature, elastic constants, and strength. The polymers are composed of the epoxy resin DGEBA (EPON825) and a series of cross-linkers with different number of active sites and rigidity 33DDS, 44DDS, APB133, TREN, and TAPA. Our simulations quantify effects of cross-linkers on thermal and mechanical properties.

Keywords

CROSS-LINKED EPOXY, MECHANICAL-PROPERTIES, FORCE-FIELD, THERMOMECHANICAL RESPONSE, NETWORKS, LINKING, DEFORMATION, COMPOSITES, DENSITY, RESINS

DOI

10.1007/s00707-013-1064-2

Date of this Version

4-2014

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