Location
University of Leeds
Keywords
Electrical field; TSA; Cement-based materials; Degradation process
Abstract
The thaumasite form of sulfate attack (TSA) of cement-based materials is a complex degradation process. The degradation process needs abundant water, carbonate, sulfate and silicate. However, there is no detailed study on the TSA degradation process. X-Ray Diffraction (XRD) and chemical analyses were used to study the TSA degradation process based on the present studies. The results indicated that the degradation process of the electrical field was similar to the full immersion, with the main difference being the degradation rate. The electrical field can obviously accelerate the TSA degradation process. The degradation had progressed to the core of the sample, and the amount of pulp was found at 120 days. The degree of degradation of the MgSO4 full immersion affected only the surface of the sample at 360 days. The degree of degradation of the MgSO4 full immersion was the lowest at 360 days. Meanwhile, combining the XRD, chemical analysis data, the degradation rule was summarized as there being a fixed range to generate the pulp (the representative thaumasite form of sulfate attack), and the pH and the Ca/S need to meet the following conditions: 10.60
Included in
The TSA Degradation Process Within Cement-Based Materials in the Electrical Field Environment
University of Leeds
The thaumasite form of sulfate attack (TSA) of cement-based materials is a complex degradation process. The degradation process needs abundant water, carbonate, sulfate and silicate. However, there is no detailed study on the TSA degradation process. X-Ray Diffraction (XRD) and chemical analyses were used to study the TSA degradation process based on the present studies. The results indicated that the degradation process of the electrical field was similar to the full immersion, with the main difference being the degradation rate. The electrical field can obviously accelerate the TSA degradation process. The degradation had progressed to the core of the sample, and the amount of pulp was found at 120 days. The degree of degradation of the MgSO4 full immersion affected only the surface of the sample at 360 days. The degree of degradation of the MgSO4 full immersion was the lowest at 360 days. Meanwhile, combining the XRD, chemical analysis data, the degradation rule was summarized as there being a fixed range to generate the pulp (the representative thaumasite form of sulfate attack), and the pH and the Ca/S need to meet the following conditions: 10.60
