Optical studies of inorganic/organic hybrid crystals

Michael Christoffel Rifani, Purdue University

Abstract

Inorganic/Organic Hybrid Crystals (IOHCs) have emerged as new materials with applications in optics. The present study aims at characterizing the fluorescence and stimulated emission of these inclusions. We demonstrated Q-switched-pumped laser operations using IOHCs, and we devised a modified saturation intensity analysis to extract the spontaneous emission lifetime of the media. We investigated a reversible, temperature-dependent, solvatochromic interaction of a basic pyrene inclusion in K2SO4. We characterized a fluorescence quenching at cryogenic temperatures of sulforhodamine inclusions. Finally, we searched for the spectral fine structure in the sulforhodamine B inclusion.

Degree

Ph.D.

Advisors

Elliott, Purdue University.

Subject Area

Electrical engineering|Optics|Organic chemistry

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