Effect of Temperature on the Sustainability of Eco-Engineered Cementitious Composites: Curing, Extreme Conditions and Service Life
Abstract
With over 30 billion tons of global annual production, concrete is the most used construction material in the world. Its manufacturing is associated with a strong environmental impact due to the high natural resources’ consumption, energy consumption, and a large generation of wastes and pollutants with significant global consequences. There are many different approaches to reduce the environmental impact of cementitious materials. Two examples are: (i) the use of recycled aggregate (RA) such as recycled concrete aggregate (RCA) and recycled plastics, or supplementary cementitious materials (SCMs) such as biomass ashes to reduce the use of natural aggregates and cement, respectively, and (ii) using nano-additives (for instance, nanoTiO2) to enhance material’s performance and to provide the material new properties that may have a positive proactive effect during its service life (i.e., photocatalytic properties that may reduce different pollutants concentrations from the environment). These approaches have been widely studied in standard conditions. However, boundary conditions such as temperature or moisture can be critical factors that directly or indirectly affect the effect of these approaches on the sustainability of cementitious composites in all stages of their life, from curing to service conditions.It is known that curing temperature influences the effect of using recycled materials (such as RCA or SCMs) on the mechanical properties of cementitious materials. However, there were no studies concerning the influence of curing temperature on the nano-TiO2 addition effect on mechanical properties of cementitious composites. A potential change will affect composites’ sustainability; if curing temperature influences the effect of nano-TiO2 on strength, the cement content needed to achieve a given performance will variate. This study concluded that curing temperature is a key factor that changes the effect of TiO2 nanoparticles on mechanical properties and pore structure of Portland cement mortars; the lower the curing temperature, the higher the positive effect of TiO2on compressive strength.Besides the use of nano-TiO2, the substitution of NA with RCA might significantly benefit the sustainability of cementitious composites. However, the use of RCA may lead to a reduction in strength. On the other hand, the addition of nano-TiO2 mixtures containing RCA might offset this reduction in strength. Nevertheless, studying their effects on the composites’ performance under extreme conditions is critical to assess the actual environmental impact since durability is one of the main pillars of cementitious materials sustainability. This study concluded that even though RCA may be beneficial to increase sustainability aspects in terms of net waste generation and natural abiotic depletion, its potential negative effects on high-temperature resistance should be considered to not lead to structural problems during its lifetime, especially if used in combination with nano-TiO2. The addition of low percentages of nano-TiO2 has a negative effect on the high-temperature resistance of mortar containing 100% RCA. Differences in thermal properties between old aggregate, old cement paste, and new cement paste with nano-TiO2 may induce internal stresses at high temperatures that can produce a failure at lower strength due to the weaker interfacial transition zone (ITZ) between the stronger new cement paste (with nano-TiO2) and the old cement paste.
Degree
Ph.D.
Advisors
Velay-Lizancos, Purdue University.
Subject Area
Energy|Natural Resource Management|Sustainability
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