Evaluation of Adhesive Bonding for HVAC&R Applications
Abstract
In the heating, ventilation, air conditioning and refrigeration (HVAC&R) industry, bonding and joining play an important role in the manufacturing and assembly process, which is critical to the cost, safety, reliability, and design freedom of systems. The goal of this thesis is to understand and evaluate the usage of adhesive bonds in the manufacture of HVAC&R systems, specifically in regards to leakage/reliability characterization and stress analysis under loading. The bonding performance under static loading is first studied using a commercial epoxy adhesive product. In addition to the traditional surface preparation methods of mechanical and chemical etching, a novel laser-interference surface structuring preparation technique was utilized to improve bonding performance. Laser interference structuring uses a ND:YAG laser beam that is split into two beams that are re-directed to overlap on the same area of a copper alloy. A structuring pattern near the interference structuring limits is achieved due to the phase shift between the beams that is imparted as they are re-directed. Two different laser structuring methods were tested: spot-by-spot and laser raster. Different structuring parameters were varied including the laser spot size and pulses per spot (2, 4, 6, 8, 10, 12 pulses/spot) for the spot-by-spot method, and raster speed (2, 4, 6, 8, 10, 12 mm/s) for laser raster method. The microstructure morphology and surface profile after processing were characterized using the scanning electron microscopy (SEM) and profilometry for all surfaces. It was found that the laser-interference structuring removed the surface contaminants efficiently and formed dot- or net-shaped structures on the surface. This indicates that melting, vaporization, and solidification of the metal happened differently. Due to the much higher speed of the laser raster method, considering practical industrial applications, it is selected for additional investigation for shear strength improvement. The shear strength is measured by a single lap shear test which pulls apart adhesively bonded single lap joint specimen under shear loading using a mechanical tester. Based on the surface profiles, three different laser raster speeds of 2 mm/s, 6 mm/s and 12 mm/s were selected for the manufacture of single lap joint specimens for comparison with the traditional surface preparation methods. The shear lap strength and displacement at maximum load were obtained for the specimens. The laser raster at 6 mm/s increased these values by approximately 11.0% and 25.1%, respectively, while the 12 mm/s condition had an increase of 16.8% and 43.8%, compared with the baseline traditional surface preparation method. It is concluded that laser structuring can enhance the single lap shear joint bonding performance. Within the tested laser processing parameters, a higher laser raster speed results in a larger enhancement. In addition to the static loading test with epoxy adhesive, different adhesive formulations are investigated and developed by the collaborating adhesive manufacturer to determine their suitability for use underthe temperature and pressure conditions in HVAC&R systems. Reliability, especially fatigue failure, is another major concern because the strength of the adhesive joints is sufficient for HVAC&R applications. Two primary types of fatigue may happen in practical applications: thermal fatigue and vibration fatigue.
Degree
Ph.D.
Advisors
Weibel, Purdue University.
Subject Area
Design|Analytical chemistry|Chemistry|Climate Change|Energy|Environmental Health|Labor relations|Materials science|Mathematics|Thermodynamics
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