Droplet Heat and Mass Exchange with the Ambient During Dropwise Condensation and Freezing

Julian Castillo, Purdue University

Abstract

The distribution of local water vapor in the surrounding air has been shown to be the driving mechanism for several phase change phenomena during dropwise condensation and condensation frosting. This thesis uses reduced-order modeling approaches, which account for the effects of the vapor distribution to predict the droplet growth dynamics during dropwise condensation in systems of many droplets. High-fidelity modeling techniques are used to further probe and quantify the heat and mass transport mechanisms that govern the local interactions between a freezing droplet and its surrounding ambient, including neighboring droplets. The relative significance of these transport mechanisms in the propagation of frost are investigated. A reduced-order analytical method is first developed to calculate the condensation rate of each individual droplet within a group of droplets on a surface by resolving the vapor concentration field in the surrounding air. A point sink superposition method is used to account for the interaction between all droplets without requiring solution of the diffusion equation for a full three-dimensional domain. For a simplified scenario containing two neighboring condensing droplets, the rates of growth are studied as a function of the inter-droplet distance and the relative droplet size. Interactions between the pair of droplets are discussed in terms of changes in the vapor concentration field in the air domain around the droplets. For representative systems of condensing droplets on a surface, the total condensation rates predicted by the reduced-order model match numerical simulations to within 15%. The results show that assuming droplets grow as an equivalent film or in a completely isolated manner can severely overpredict condensation rates.The point superposition model is then used to predict the condensation rates measured during condensation experiments. The results indicate that it is critical to consider a large number of interacting droplets to accurately predict the condensation behavior. Even though the intensity of the interaction between droplets decreases sharply with their separation distance, droplets located relatively far away from a given droplet must be considered to accurately predict the condensation rate, due to the large aggregate effect of all such far away droplets. By considering an appropriate number of interacting droplets in a system, the point sink superposition method is able to predict experimental condensation rates to within 5%. The model was also capable of predicting the timevarying condensation rates of individual droplets tracked over time. These results confirm that diffusion-based models that neglect the interactions of droplets located far away, or approximate droplet growth as an equivalent film, overpredict condensation rates.In dropwise condensation from humid air, a full description of the interactions between droplets can be determined by solving the vapor concentration field while neglecting heat transfer across the droplets. In contrast, the latent heat released during condensation freezing processes cause droplet-to-ambient as well as droplet-to-droplet interactions via coupled heat and mas transfer processes that are not well understood, and their relative significance has not been quantified. As a first step in understanding these mechanisms, high-fidelity modeling of the solidification process, along with high-resolution infrared (IR) thermography measurements of the surface of a freezing droplet, are used to quantify the pathways for latent heat dissipation to the ambient surroundings of a droplet.

Degree

Ph.D.

Advisors

Weibel, Purdue University.

Subject Area

Atmospheric sciences|Fluid mechanics|Mathematics|Mechanics|Thermodynamics

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