Direct simulation Monte Carlo study of effects of thermal nonuniformities in electron-beam physical vapor deposition

A. Venkattraman, Purdue University
Alina A. Alexeenko, Birck Nanotechnology Center, Purdue University

Date of this Version

7-2011

Citation

Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. Volume 29, Issue 4. 10.1116/1.3592890

Comments

Copyright (2011) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Journal of Vacuum Science & Technology A Volume 29, Issue 4 and may be found at http://dx.doi.org/10.1116/1.3592890. The following article has been submitted to/accepted by Journal of Vaccuum Science & Technology. Copyright (2011) A. Venkattraman Alina A. Alexeenko. This article is distributed under a Creative Commons Attribution 3.0 Unported License.

Abstract

In a typical electron-beam physical vapor deposition system, there is limited control over how the high-power electron beam heats the metal surface. This leads to thermal nonuniformities at the melt. Three-dimensional direct simulation Monte Carlo simulations were performed with the aim of quantifying the effect of such spatial variations of source temperature in thin film depositions using an electron-beam physical vapor deposition system. The source temperature distribution from a typical deposition process was used in the direct simulation Monte Carlo simulations performed for various mass flow rates. The use of an area-averaged temperature is insufficient for all mass flow rates due to the highly nonlinear relationship between temperature and saturation number density, and hence, the mass flux. The mass flow rate equivalent temperature was determined, and the simulations performed with this temperature were compared with those corresponding to the actual nonuniform temperature distribution. For low mass flow rates, the growth rates depend very weakly on the spatial variation of temperature as long as an equivalent temperature corresponding to the same mass flow rate was used. However, as the mass flow rate increases, the error associated with this approximation increases. For deposition processes with source Knudsen numbers less than 0.05, it is not possible to account for the spatial nonuniformities in temperature using the total mass flow rate without significant errors. For a given mass flow rate, the errors associated with using an equivalent temperature decrease with increasing collector plane distance since the flow is allowed to expand further, thereby decreasing the effects of slit temperature nonuniformities. (C) 2011 American Vacuum Society. [DOI: 10.1116/1.3592890]

Discipline(s)

Nanoscience and Nanotechnology

 

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