Abstract

Mechanoresponsive color-changing materials that can reversibly and resiliently change color in response to mechanical deformation are highly desirable for diverse modern technologies in optics, sensors, and robots; however, such materials are rarely achieved. Here, a fatigue-resistant mechanoresponsive color-changing hydrogel (FMCH) is reported that exhibits reversible, resilient, and predictable color changes under mechanical stress. At its undeformed state, the FMCH remains dark under a circular polariscope; upon uniaxial stretching of up to six times its initial length, it gradually shifts its color from black, to gray, yellow, and purple. Unlike traditional mechanoresponsive color-changing materials, FMCH maintains its performance across various strain rates for up to 10 000 cycles. Moreover, FMCH demonstrates superior mechanical properties with fracture toughness of 3000 J m−2, stretchability of 6, and fatigue threshold up to 400 J m−2. These exceptional mechanical and optical features are attributed to FMCH's substantial molecular entanglements and desirable hygroscopic salts, which synergistically enhance its mechanical toughness while preserving its color-changing performance. One application of this FMCH as a tactile sensoris then demonstrated for vision-based tactile robots, enabling them to discern material stiffness, object shape, spatial location, and applied pressure by translating stress distribution on the contact surface into discernible images.

Comments

This is the publisher PDF of Jiabin Liu, Wei Li, Yu She, Shaoting Lin, “Fatigue-resistant Mechanoresponsive Photonic Hydrogels for Vision-based Tactile Robots,” Advanced Materials, 2024. Published CC-BY through Wiley, the version of record is at DOI: 10.1002/adma.202407925.

Date of this Version

9-27-2024

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